Download B Boron Compounds: 4th Supplement Volume 2, Boron and Oxygen by Gert Heller (auth.), Jürgen Faust, Kurt Niedenzu (eds.) PDF

By Gert Heller (auth.), Jürgen Faust, Kurt Niedenzu (eds.)

The current factor, quantity 2 of "Boron Compounds" 4th complement of the Gmelin Hand­ booklet, updates the former concerns by means of reporting the literature on boron-oxygen platforms released as much as 1988. For a few very important fresh advancements literature is roofed via mid-1992; this matters, for instance, the compounds ~-Ba3[B306h and U[B305J which grew to become of curiosity as fabrics with nonlinear optical houses. the amount at once com­ plements the sooner "Boron Compounds" third complement quantity 2. within the unique literature, substitute formulations are usually used for a similar com­ pound. this can be very true for lots of borates. frequently, those species are neither thoroughly heteropolar nor covalent, and an experimentally dependent selection has no longer been made. as a result, using brackets doesn't inevitably replicate a really salt-like personality. quantity 1 (systems with hydrogen and noble gases) of this actual complement may be released as a result, while quantity 3a (boron and nitrogen), quantity 3b (boron and nitrogen, boron and fluorine), and quantity four (boron compounds containing Cl, Br, I, S, Se, and Te, in addition to a bit containing carboranes) have already been released. All volumes of the 4th complement might be augmented through a formulation index. The IUPAC nomenclature is mostly adhered to; thf capability tetrahydrofuran; and occa­ sionally extra abbreviations for compounds are defined within the textual content. optimistic symptoms for chemical shifts of the NMR signs exhibits downfield shifts from the references, often inner (CH3)4Si for olH and 013C with others being specified.

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Extra info for B Boron Compounds: 4th Supplement Volume 2, Boron and Oxygen

Example text

Heating of controlled porous glass (CPG) between 400 and 700·C not only leads to a dehydroxylation process on the surface but also brings about a diffusion of the boron atoms remaining in the silica network of CPG towards the glass surface. Some authors assume that a long thermal exposure can cause the formation of B2 0 3 crystals in the pores, but small angle X-ray scattering (SAXS) data led to pore size distribution functions that show the crystallites being x Na20· y B2 0 3 (y > x) rather than B2 0 3 [16].

Simkin, V. ; Dement'ev, A. I. (Eesti NSV Tead. Akad. Toim. Keem. 34 [1985] 231/4). ; Simkin, V. ; Dement'ev, A. ; Stepanov, N. F. (Eesti NSV Tead. Akad. Toim. Keem. 34 [1985] 235/6). ; Simkin, V. ; Stepanov, N. F. (Zh. Fiz. Khim. 60 [1986] 1162/5; Russ. J. Phys. Chem. 60 [1986/87] 694/6). [16] Zyubina, T. S. (Zh. Neorg. Khim. 30 [1985] 112114; Russ. J. Inorg. Chem. 30 [1985] 633/5). [17] Nguyen, M. T. (Mol. Phys. 58 [1986] 655/8). ; Diamond, J. ; Segal, G. A. (J. Phys. Chem. 87 [1983] 718/9).

Ugai, Va. A. (J. Less-Common Met. 117 [1986] 277/81). ; Haupt, H. (Z. Naturforsch. 428 [1987] 925/34). ; Thevenot, F. (J. Less-Common Met. 117 [1987] 1/6). Zyubina, T. ; Charkin, O. ; Zyubin, A. ; Zakzhevskii, V. G. (Z. Neorg. Khim. 27 [1982] 558/64; Russ. J. Inorg. Chem. 27 [1982] 315/8). Woodward, R. ; Le, P. ; GoLe, J. L. (J. Phys. Chem. 91 [1987] 2637/45). Devore, T. ; Woodward, R. ; GoLe, J. L. (J. Phys. Chem. 92 [1988] 6919/23). NationaL Institute of Research of Inorganic MateriaLs (Jpn.

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